relation: https://khub.utp.edu.my/scholars/13935/
title: RETRACTED ARTICLE: Study on the influence of Mg and catalytic activity of SAPO-34 on biodiesel production from rambutan seed oil
creator: Abdulkadir, B.A.
creator: Ramli, A.
creator: Lim, J.W.
creator: Uemura, Y.
description: In this study, the effect of Mg impregnated into microporous SAPO-34 on catalytic activity was investigated for biodiesel production from rambutan seed oil. The modification of the support was conducted by a wet impregnation process, and the modified catalyst was calcined at 500 °C for 3 h and characterized by X-ray diffraction (XRD), N2 physisorption and TPD-NH3 for crystal phase, textural properties and acidic behavior, respectively. The transesterification process was conducted with rambutan seed oil to test the effectiveness of the catalyst and to investigate the effect of Mg loading on the surface of the parent support, SAPO-34. The presence of Mg was confirmed by the XRD results. The N2 physisorption results showed a decrease in surface area from 508 to 373 m2/g after the incorporation of a high percentage of Mg, while acidic strength decreased with increased Mg loading. The optimization results and conditions that achieved the highest fatty acid methyl ester (FAME) yield of 90.7 were 15 wt Mg loading, 80 °C reaction temperature, 3.0 wt catalyst loading, 15:1 methanol:oil molar ratio and 100 min reaction time. A drop in catalyst activity (15 wt Mg/SAPO-34) of only about 4 was observed during the reusability studies after three consecutive runs. This makes 15 wt Mg/SAPO-34 a suitable catalyst for transesterification. © 2019 Informa UK Limited, trading as Taylor & Francis Group.
publisher: Taylor and Francis Ltd.
date: 2020
type: Article
type: PeerReviewed
identifier:   Abdulkadir, B.A. and Ramli, A. and Lim, J.W. and Uemura, Y.  (2020) RETRACTED ARTICLE: Study on the influence of Mg and catalytic activity of SAPO-34 on biodiesel production from rambutan seed oil.  Biofuels.   ISSN 17597269     
relation: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85082706702&doi=10.1080%2f17597269.2019.1583715&partnerID=40&md5=12a12e41ce204e24b0069bf4c3eb7d4d
relation: 10.1080/17597269.2019.1583715
identifier: 10.1080/17597269.2019.1583715