%0 Conference Paper %A Mat-Shayuti, M.S. %A Megat-Yusoff, P.S.M. %A Sharudin, R.W. %A Wan Bakar, W.Z. %A Jarni, H.H. %A Ahmad Fuad, F.I. %D 2020 %F scholars:13582 %I Elsevier Ltd %K Activation energy; Cooking; Gas chromatography; Mass spectrometry; Oils and fats; Polystyrenes, Arrhenius models; Calibration curves; Carcinogenics; Cooking oil; Distilled water; DSC; Food contaminants; FTIR; Lipid/fat; Styrene monomer, Styrene %P 1350-1354 %R 10.1016/j.matpr.2021.03.530 %T Arrhenius model for styrene monomer migration from single-use polystyrene cup %U https://khub.utp.edu.my/scholars/13582/ %V 47 %X Harmful chemicals leaching into beverage contained in polystyrene (PS) cup is a concern for consumers, therefore this paper seeks to investigate the pattern of styrene monomers migration with respect to temperature. PS cups containing liquid stimulants (distilled water & cooking oil) were subjected to temperatures of 25-100 °C. Gas chromatography-mass spectrometry (GC-MS) showed no hint of styrene in distilled water but detected styrene traces in the cooking oil to be proportional with temperature. The migration rate jumped above 75 °C, suggesting a threshold point for enhanced styrene absorption. This could be attributed to the compromised structural integrity of the cup and greater styrene solubility in the cooking oil above 75 °C. The activation energy required for styrene migration from the PS cup computed through Arrhenius equation was 12.117 kJ/mol. Despite the finding, the highest recorded styrene content which was 1.1158 � 10-4wt at 100 °C still fell below the maximum allowable limit of 0.5 wt set by the U.S. Food and Drug Administration (FDA). © 2020 Elsevier Ltd. All rights reserved. %Z cited By 2; Conference of 3rd International Conference on Separation Technology, ICoST 2020 ; Conference Date: 15 August 2020 Through 16 August 2020; Conference Code:171967