eprintid: 13494
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/34/94
datestamp: 2023-11-10 03:28:03
lastmod: 2023-11-10 03:28:03
status_changed: 2023-11-10 01:51:19
type: article
metadata_visibility: show
creators_name: Azeem, B.
creators_name: KuShaari, K.
creators_name: Naqvi, M.
creators_name: Keong, L.K.
creators_name: Almesfer, M.K.
creators_name: Al-Qodah, Z.
creators_name: Naqvi, S.R.
creators_name: Elboughdiri, N.
title: Production and characterization of controlled release urea using biopolymer and geopolymer as coating materials
ispublished: pub
keywords: Atmospheric temperature; Biodegradable polymers; Biomolecules; Biopolymers; Coatings; Genetic algorithms; Geopolymers; Inorganic polymers; Metabolism; Multiobjective optimization; Plating; Pollution control; Starch; Urea; Urea fertilizers, Controlled release; Fluidized bed coating; Green fertilizer; Nitrogen release; Rotary fluidized bed coater, Fluidized beds
note: cited By 52
abstract: Synthetic polymers-based controlled release urea (CRU) leaves non-biodegradable coating shells when applied in soil. Several alternative green materials are used to produce CRU, but most of these studies have issues pertaining to nitrogen release longevity, process viability, and the ease of application of the finished product. In this study, we utilized tapioca starch, modified by polyvinyl alcohol and citric acid, as coating material to produce controlled release coated urea granules in a rotary fluidized bed equipment. Response surface methodology is employed for studying the interactive effect of process parameters on urea release characteristics. Statistical analysis indicates that the fluidizing air temperature and spray rate are the most influential among all five process parameters studied. The optimum values of fluidizing air temperature (80 °C), spray rate (0.13 mL/s), atomizing pressure (3.98 bar), process time (110 min), and spray temperature (70 °C) were evaluated by multi-objective optimization while using genetic algorithms in MATLAB®. Urea coated by modified-starch was double coated by a geopolymer to enhance the controlled release characteristics that produced promising results with respect to the longevity of nitrogen release from the final product. This study provides leads for the design of a fluidized bed for the scaled-up production of CRU. © 2020 by the authors. All rights reserved.
date: 2020
publisher: MDPI AG
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85080048804&doi=10.3390%2fpolym12020400&partnerID=40&md5=9222fd4b46c7867f49c4cc145171f75a
id_number: 10.3390/polym12020400
full_text_status: none
publication: Polymers
volume: 12
number: 2
refereed: TRUE
issn: 20734360
citation:   Azeem, B. and KuShaari, K. and Naqvi, M. and Keong, L.K. and Almesfer, M.K. and Al-Qodah, Z. and Naqvi, S.R. and Elboughdiri, N.  (2020) Production and characterization of controlled release urea using biopolymer and geopolymer as coating materials.  Polymers, 12 (2).   ISSN 20734360