%0 Journal Article %@ 19342659 %A Sudesh, S. %A Meenakshi, M. %A Sheeja, R.Y. %A Murugesan, T. %D 2010 %F scholars:1314 %J Chemical Product and Process Modeling %K Aqueous solutions; Batch experiments; Biosorbents; Box-Behnken design; Copper concentration; Correlation coefficient; Crab shell; Crab shells; Experimental data; Experimental values; Initial pH; Optimization studies; Quadratic regression; Response surface method; Response Surface Methodology; Second orders, Biosorption; Mathematical models; Optimization; Regression analysis; Shells (structures); Surface properties, Copper %N 1 %R 10.2202/1934-2659.1357 %T Optimization studies on biosorption of copper (II) by crab shell using response surface methodology(RSM) %U https://khub.utp.edu.my/scholars/1314/ %V 5 %X In the present work, crab shell was used as the biosorbent to remove copper from aqueous solution. Batch experiments were performed at different initial copper concentration of copper solutions (1-40 g/l), initial pH (2-9), temperature (20-400°C), and biosorbent dosages (2-10 g/l). The maximum removal of copper using crab shell occurred at a pH of 3 and at a temperature of 400°C using an optimum biosorbent dosage of 5 g/l. A mathematical model was proposed to identify the effects of the individual interactions of these variables on the biosorption of copper. The results have been modeled using response surface methodology using a Box-Behnken design. The response surface method was developed using three levels (-1, 0, +1) with the above mentioned four factors. The second order quadratic regression model fitted the experimental data with Prob > F to be < 0.0001. The experimental values were found to be in good agreement with the predicted values, with a satisfactory correlation coefficient of R2= 0.9999. © 2010 The Berkeley Electronic Press. All rights reserved. %Z cited By 1