eprintid: 13130
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/31/30
datestamp: 2023-11-10 03:27:41
lastmod: 2023-11-10 03:27:41
status_changed: 2023-11-10 01:50:25
type: article
metadata_visibility: show
creators_name: Zubair, N.A.
creators_name: Nasef, M.M.
creators_name: Mohamad, N.A.
creators_name: Abouzari-Lotf, E.
creators_name: Ting, T.M.
creators_name: Abdullah, E.C.
title: Kinetic studies of radiation induced grafting of N-vinylformamide onto polyethylene/polypropylene fibrous sheets and testing its hydrolysed copolymer for CO2 adsorption
ispublished: pub
keywords: Carbon dioxide; Fourier transform infrared spectroscopy; Hydrolysis; Kinetics; Monomers; Polyethylenes; Polypropylenes; Reaction kinetics; Scanning electron microscopy; X ray photoelectron spectroscopy, CO2 adsorbents; Grafting kinetics; Non-woven; Radiation-induced grafting; Vinylformamide, Grafting (chemical), carbon dioxide; formamide derivative; monomer; n vinylformamide; poly(vinylamine); polyethylene; polypropylene; unclassified drug, adsorption; Article; chemical interaction; chemical modification; chemical parameters; chemical reaction kinetics; chemical structure; concentration (parameter); Fourier transform infrared spectroscopy; hydrolysis; polymerization; pressure; quantitative analysis; radiation dose; radiological procedures; reaction temperature; room temperature; scanning electron microscopy; time factor; X ray photoemission spectroscopy
note: cited By 12
abstract: Kinetics of the grafting process is highly important for understanding reaction mechanism pertaining graft copolymer preparation quality, reproducibility and economics. In this study, the kinetic behaviour of grafting of N-vinylformamide (NVF) monomer onto polyethylene coated polypropylene (PE/PP) fibrous sheet was investigated with respect to the dependence of degree of grafting (G) on various reaction parameters like monomer concentration, absorbed dose, and reaction temperature for the first time. The kinetic analysis covered not only the initial polymerisation rate (rp0), radical recombination rate and delay time (t0) but also orders evaluations of the grafting rate dependence on the monomer concentration, absorbed dose and temperature. The chemical and morphological changes caused by the inclusion of poly(NVF) grafts into PE/PP substrates were monitored by Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). The results of the present study led to the establishment of a quantitative kinetic description for grafting of NVF onto PE/PP and demonstrated that the degree of grafting is strongly dependent on the investigated reaction parameters. The adsorbent containing poly(vinylamine) obtained by the hydrolysis of the grafted poly(NVF) chains showed a remarkable CO2 adsorption capacity of 1.36 mmol/g at room temperature and a pressures of 30 bar. © 2020 Elsevier Ltd
date: 2020
publisher: Elsevier Ltd
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85078664559&doi=10.1016%2fj.radphyschem.2020.108727&partnerID=40&md5=8cd104106d787b4c50a8415fc0e9b148
id_number: 10.1016/j.radphyschem.2020.108727
full_text_status: none
publication: Radiation Physics and Chemistry
volume: 171
refereed: TRUE
issn: 0969806X
citation:   Zubair, N.A. and Nasef, M.M. and Mohamad, N.A. and Abouzari-Lotf, E. and Ting, T.M. and Abdullah, E.C.  (2020) Kinetic studies of radiation induced grafting of N-vinylformamide onto polyethylene/polypropylene fibrous sheets and testing its hydrolysed copolymer for CO2 adsorption.  Radiation Physics and Chemistry, 171.   ISSN 0969806X