eprintid: 12882
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/28/82
datestamp: 2023-11-10 03:27:26
lastmod: 2023-11-10 03:27:26
status_changed: 2023-11-10 01:49:46
type: article
metadata_visibility: show
creators_name: Toh, M.J.
creators_name: Oh, P.C.
creators_name: Chew, T.L.
creators_name: Ahmad, A.L.
title: Preparation of polydimethylsiloxane-SiO2/PVDF-HFP mixed matrix membrane of enhanced wetting resistance for membrane gas absorption
ispublished: pub
keywords: Carbon dioxide; Contact angle; Hydrophobicity; Membranes; Nanoparticles; Phase separation; Silica; Silicones; Wetting, Hierarchical structures; Hydrophobic membrane; Interfacial areas; Membrane gas absorption; Membrane matrix; Mixed matrix membranes; Solvent additives; Water contact angle, Gas absorption
note: cited By 20
abstract: Membrane gas absorption (MGA) has been widely used to separate CO2 from gas mixture attributed to its high interfacial area. In order to secure high absorption flux, the pores of the membrane need to be non-wetted. Currently, hydrophobic membrane suffers from severe pore wetting over prolonged periods of operation. This has called for the enhancement of membrane hydrophobicity to suppress the tendency of pore wetting. In this work, highly hydrophobic PVDF-HFP membrane was synthesized using solvent additive i.e. polydimethylsiloxane-grafted-silica (PGS) via non-solvent induced phase separation. Results showed that mixed matrix membranes (MMMs) exhibited hierarchical structure composed of polymer spherulites due to delayed phase inversion. The embedment of nanoparticles in membrane matrix also contributed to the reduction of membrane's surface energy. As a result, MMMs achieved an improvement in wetting resistance with a water contact angle up to 149.87° at 3 wt of PGS nanoparticles. The CO2 absorption test using MEA as liquid absorbent showed that MMMs exhibited an enhancement in gas absorption flux owing to higher hydrophobicity. The CO2 absorption flux of pristine and MMMs was declined about 37 and 22, respectively during 150 h of operation. © 2020 Elsevier B.V.
date: 2020
publisher: Elsevier B.V.
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85083337889&doi=10.1016%2fj.seppur.2020.116543&partnerID=40&md5=9ff84bf78e0af080021ded75cd93eb64
id_number: 10.1016/j.seppur.2020.116543
full_text_status: none
publication: Separation and Purification Technology
volume: 244
refereed: TRUE
issn: 13835866
citation:   Toh, M.J. and Oh, P.C. and Chew, T.L. and Ahmad, A.L.  (2020) Preparation of polydimethylsiloxane-SiO2/PVDF-HFP mixed matrix membrane of enhanced wetting resistance for membrane gas absorption.  Separation and Purification Technology, 244.   ISSN 13835866