TY - JOUR SN - 03043894 EP - 758 AV - none SP - 749 TI - Statistical optimization of process parameters for landfill leachate treatment using electro-Fenton technique N1 - cited By 253 Y1 - 2010/// VL - 176 UR - https://www.scopus.com/inward/record.uri?eid=2-s2.0-74449086327&doi=10.1016%2fj.jhazmat.2009.11.099&partnerID=40&md5=d7185bbe35ef28f4d32fcd95a0d59bb4 A1 - Mohajeri, S. A1 - Aziz, H.A. A1 - Isa, M.H. A1 - Zahed, M.A. A1 - Adlan, Mohd.N. JF - Journal of Hazardous Materials KW - Color removal; Desirability function; Electro-Fenton; Electro-Fenton process; Fenton process; High concentration; Landfill leachate treatment; Landfill leachates; Molar ratio; Numerical optimizations; Operating parameters; Organics; Process parameters; Quadratic polynomial; Reaction time; Recalcitrant organics; Response Surface Methodology; Semi-aerobic landfill; Statistical optimization KW - Color; Leaching; Optimization; Refuse disposal; Removal; Surface properties KW - Leachate treatment KW - glass; hydrogen peroxide; iron; metal; oxygen; plastic KW - chemical oxygen demand; landfill; leachate; methodology; modeling; optimization; pollutant removal; reaction rate; waste treatment KW - article; biodegradability; chemical oxygen demand; controlled study; decolorization; density; Fenton reaction; landfill leachate; mathematical model; pH; process optimization; reaction time; response surface method; solid waste KW - Color; Electrochemical Techniques; Environmental Remediation; Hydrogen Peroxide; Hydrogen-Ion Concentration; Kinetics; Organic Chemicals; Water Pollutants KW - Chemical; Water Purification ID - scholars1275 N2 - Mature landfill leachate is typically non-biodegradable and contains high concentration of refractory organics. The aim of this research was to optimize operating parameters in electro-Fenton process, for the removal of recalcitrant organics from semi-aerobic landfill leachate using response surface methodology (RSM). Effectiveness of important process parameters H2O2/Fe2+ molar ratio, current density, pH and reaction time were determined, optimized and modeled successfully. Significant quadratic polynomial models were obtained (R2 = 0.9972 and 0.9984 for COD and color removals, respectively). Numerical optimization based on desirability function were employed; in a 43 min trial 94.07 of COD and 95.83 of color were removed at pH 3 and H2O2/Fe2+ molar ratio 1, while current density was 49 mA/cm2. The results indicate that E-Fenton process was an effective technology for semi-aerobic landfill leachate treatment. © 2009 Elsevier B.V. All rights reserved. IS - 1-3 ER -