eprintid: 12442 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/01/24/42 datestamp: 2023-11-10 03:26:59 lastmod: 2023-11-10 03:26:59 status_changed: 2023-11-10 01:48:46 type: article metadata_visibility: show creators_name: Tiong, A.C.Y. creators_name: Tan, I.S. creators_name: Foo, H.C.Y. creators_name: Lam, M.K. creators_name: Mahmud, H.B. creators_name: Lee, K.T. title: Macroalgae-derived regenerated cellulose in the stabilization of oil-in-water Pickering emulsions ispublished: pub keywords: Cellulose; Emulsification; Ostwald ripening; Paraffin oils; Stabilization, Cluster interactions; Enhanced oil recovery; Fibrillar morphology; Materials interaction; Oil water interfaces; Pickering emulsions; Regenerated cellulose; Structure formations, Enhanced recovery, Behavior; Emulsification; Emulsions; Oil; Regenerated Cellulose; Stabilization; Water note: cited By 14 abstract: This study aims to derive regenerated cellulose (RC) from lignin/hemicellulose-free Eucheuma cottonii for its independent stabilization of Pickering emulsion. The RC exhibits a fibrillar morphology with diameters ranging from 17 to 157 nm and stabilizes paraffin oil-Pickering emulsions without any co-stabilizer. It was found that the emulsion stability, viscosities and viscoelasticity correlate positively with RC concentration. All emulsion samples depict gel-like behavior. Under different oil fraction at a constant RC concentration, anomalies were found in emulsion properties. This can be attributed to the aggregating behavior of RC at the oil-water interface, the degree of gel-like structure formation due to materials interaction within the emulsion system, and the variations of microscopic droplet cluster interactions under shear condition. The emulsions portrayed excellent robustness against harsh salinity, high temperature and extreme pH fluctuation. Hence, these findings had elucidated the plausibility of macroalgae-derived RC in enhanced oil recovery application. © 2020 Elsevier Ltd date: 2020 publisher: Elsevier Ltd official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85089266146&doi=10.1016%2fj.carbpol.2020.116875&partnerID=40&md5=a8368c77b74fdb38b98f43f381210e9e id_number: 10.1016/j.carbpol.2020.116875 full_text_status: none publication: Carbohydrate Polymers volume: 249 refereed: TRUE issn: 01448617 citation: Tiong, A.C.Y. and Tan, I.S. and Foo, H.C.Y. and Lam, M.K. and Mahmud, H.B. and Lee, K.T. (2020) Macroalgae-derived regenerated cellulose in the stabilization of oil-in-water Pickering emulsions. Carbohydrate Polymers, 249. ISSN 01448617