eprintid: 12345
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/23/45
datestamp: 2023-11-10 03:26:53
lastmod: 2023-11-10 03:26:53
status_changed: 2023-11-10 01:48:35
type: article
metadata_visibility: show
creators_name: Mukhtar, A.
creators_name: Saqib, S.
creators_name: Mellon, N.B.
creators_name: Rafiq, S.
creators_name: Babar, M.
creators_name: Ullah, S.
creators_name: Muhammad, N.
creators_name: Khan, A.L.
creators_name: Ayoub, M.
creators_name: Ibrahim, M.
creators_name: Maqsood, K.
creators_name: Bustam, M.A.
creators_name: Al-Sehemi, A.G.
creators_name: Klemeš, J.J.
creators_name: Asif, S.
creators_name: Bokhari, A.
title: A review on CO2 capture via nitrogen-doped porous polymers and catalytic conversion as a feedstock for fuels
ispublished: pub
keywords: Carbon monoxide; Catalysis; Cost effectiveness; Doping (additives); Energy efficiency; Gas adsorption; Hydrothermal synthesis; Nitrogen; Precombustion, Adsorption process; Assessment criteria; Catalytic conversion; Evaluation criteria; Physico-chemical stability; Real-time application; Scalable synthesis; Scientific community, Carbon dioxide
note: cited By 44
abstract: The minimisation of the continuously enhancing level of the CO2 released to the atmosphere is one of the most significant issues faced by the scientific community. Rigorous research efforts have been carried out for the development of sustainable and cost-effective nitrogen-rich porous adsorbent materials for energy-efficient and enhanced polar gas separation, i.e. pre-combustion and post-combustion CO2 capture. Among different porous adsorbent materials, the covalent triazine frameworks (CTFs) are found to be remarkable candidates for CO2 capturing because of their facile and scalable synthesis, high surface area, permanent porosity, structural tunability, synthetic diversity, low density, high hydrothermal and physicochemical stability. A contextual overview is described on the key challenges in CO2 sequestration, parameters consideration for the design of CO2 selective porous adsorbents, evaluation criteria for the adsorption processes, assessment criteria for the selection of suitable adsorption configuration, and the factors influencing the CO2 adsorption capacity. This review comprises deep critical scrutiny of the current investigation and development on Triazine-, benzimidazole-, and triazole-based COPs with improved CO2 storage capacities. The conversion of CO2 into useful products including the carbon monoxide (CO), methane (CH4), methanol (CH3OH), and other products including the hydrocarbons has been critically reviewed by using the heterogeneous catalysis. Finally, a concise conclusion and recommendation section are presented indicating that the area of Triazine-, benzimidazole-, and triazole-based COPs for CO2 capture needs more attention to synthesise the next-generation materials for real-time applications. © 2020 Elsevier Ltd
date: 2020
publisher: Elsevier Ltd
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85090947887&doi=10.1016%2fj.jclepro.2020.123999&partnerID=40&md5=e7a27ac258e2c1432298db0450c0d3ee
id_number: 10.1016/j.jclepro.2020.123999
full_text_status: none
publication: Journal of Cleaner Production
volume: 277
refereed: TRUE
issn: 09596526
citation:   Mukhtar, A. and Saqib, S. and Mellon, N.B. and Rafiq, S. and Babar, M. and Ullah, S. and Muhammad, N. and Khan, A.L. and Ayoub, M. and Ibrahim, M. and Maqsood, K. and Bustam, M.A. and Al-Sehemi, A.G. and Klemeš, J.J. and Asif, S. and Bokhari, A.  (2020) A review on CO2 capture via nitrogen-doped porous polymers and catalytic conversion as a feedstock for fuels.  Journal of Cleaner Production, 277.   ISSN 09596526