TY - JOUR N1 - cited By 35 TI - Enhanced solar light-driven photocatalytic degradation of pollutants and hydrogen evolution over exfoliated hexagonal WS2 platelets SP - 246 AV - none EP - 254 PB - Elsevier Ltd SN - 00255408 N2 - Two-dimensional (2D) layered structure transition metal dichalcogenides (TMDs) has been attracted huge attention and importance for photocatalytic energy conversion due to their unique properties. In this paper, exfoliated hexagonal WS2 (e-h-WS2) platelets were successfully synthesized by liquid-phase exfoliation (LPE) process from hexagonal WS2 (h-WS2) platelets in DMF solvent. The photocatalytic activity of e-h-WS2 and h-WS2 catalysts were compared systematically for degradation of various organic dye such as Congo red (CR), Methyl orange (MO), Phenol red (PR) and Rhodamine B (RhB)) pollutants and hydrogen production under simulated solar light irradiation. UV-vis and N2 absorption-desorption studies revealed that e-h-WS2 have shown narrow band gap and higher specific surface area than that of h-WS2. Enhanced photocatalytic activity was obtained for e-h-WS2 than h-WS2 i.e. 1.71 fold enhancement for hydrogen production rate. More importantly, this synthetic exfoliated procedure may open up an opportunity to synthesize other transition metal sulfides. © 2018 Elsevier Ltd ID - scholars12289 KW - Azo dyes; Biodegradation; Dyes; Energy conversion; Energy gap; Hydrogen production; Photocatalysis; Photocatalysts; Photodegradation; Platelets; Pollution; Solar power generation; Sulfur compounds; Transition metals KW - Absorption-desorption; Exfoliation; Hydrogen production rate; Photo catalytic degradation; Photocatalytic activities; Pollutants; Simulated solar light; Transition metal sulfides KW - Tungsten compounds A1 - Koyyada, G. A1 - Prabhakar Vattikuti, S.V. A1 - Shome, S. A1 - Shim, J. A1 - Chitturi, V. A1 - Jung, J.H. JF - Materials Research Bulletin UR - https://www.scopus.com/inward/record.uri?eid=2-s2.0-85054365519&doi=10.1016%2fj.materresbull.2018.09.045&partnerID=40&md5=637c06dfafbab817bc28a802feba162c VL - 109 Y1 - 2019/// ER -