eprintid: 12193 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/01/21/93 datestamp: 2023-11-10 03:26:44 lastmod: 2023-11-10 03:26:44 status_changed: 2023-11-10 01:17:06 type: article metadata_visibility: show creators_name: Aliyu, A.A. creators_name: Abdul-Rani, A.M. creators_name: Ginta, T.L. creators_name: Rao, T.V.V.L. creators_name: Axinte, E. creators_name: Ali, S. creators_name: Ramli, M.N. title: Hydroxyapatite electro discharge coating of Zr-based bulk metallic glass for potential orthopedic application ispublished: pub keywords: Biocompatibility; Carbides; Cell adhesion; Coatings; Glass; Hydroxyapatite; Implants (surgical); Metal implants; Metallic glass; Morphology; Orthopedics; Scanning electron microscopy; Titanium carbide; Titanium compounds; X ray spectroscopy; Zirconium compounds, Chemical compositions; Electro discharge machining; Electrodischarges; Elemental compositions; Hydroxyapatite powder; Orthopedic applications; Workpiece materials; Zr based bulk metallic glass, Phosphorus compounds note: cited By 14 abstract: In the past, Electro Discharge Machining (EDM) process was well known in cutting extremely hard materials and fabricating complex shapes. Recently, EDM process has been hybridized to not only shape, but also coats the surface of workpiece material. In this study, the deposition of hard carbide and calcium-based oxides on the Zr-based bulk metallic glass (BMG) using hydroxyapatite mixed electro discharge coating (HAm-EDC) have been investigated. The aim is to enhance the biocompatibility and cell adhesion of the BMG as a potential implant. The chemical composition, morphology and thickness of the coated surface were characterized through Optical Microscope, Scanning Electron Microscopy (SEM), X-ray Spectroscopy (EDS) and X-ray Diffraction (XRD). Major hydroxyapatite elemental composition (Ca, P, O), carbides (ZrC, TiC) and oxides (ZrO, CaZrO3) were formed on the treated BMG surface. A coating of about 23 µm thick was achieved. The addition of hydroxyapatite powder in the dielectric fluid enhances the Zr-based BMG surface quality by reducing the surface cracks and the crater size. © 2019 Trans Tech Publications, Switzerland date: 2019 publisher: Trans Tech Publications Ltd official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85064386739&doi=10.4028%2fwww.scientific.net%2fKEM.796.123&partnerID=40&md5=844b8938c3f1473fa6fe807feb96bfb0 id_number: 10.4028/www.scientific.net/KEM.796.123 full_text_status: none publication: Key Engineering Materials volume: 796 pagerange: 123-128 refereed: TRUE issn: 10139826 citation: Aliyu, A.A. and Abdul-Rani, A.M. and Ginta, T.L. and Rao, T.V.V.L. and Axinte, E. and Ali, S. and Ramli, M.N. (2019) Hydroxyapatite electro discharge coating of Zr-based bulk metallic glass for potential orthopedic application. Key Engineering Materials, 796. pp. 123-128. ISSN 10139826