eprintid: 11612
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/16/12
datestamp: 2023-11-10 03:26:08
lastmod: 2023-11-10 03:26:08
status_changed: 2023-11-10 01:15:41
type: article
metadata_visibility: show
creators_name: Nashed, O.
creators_name: Partoon, B.
creators_name: Lal, B.
creators_name: Sabil, K.M.
creators_name: Shariff, A.M.
title: Investigation of functionalized carbon nanotubes� performance on carbon dioxide hydrate formation
ispublished: pub
keywords: Carbon dioxide; Deionized water; Gas hydrates; Hydration; Kinetics; Nanotubes; Sodium dodecyl sulfate; Sulfur compounds; Thermodynamics, Carbon dioxide hydrates; Enhancement ratios; Equilibrium conditions; Functionalized carbon nanotubes; Hydrate formation; Induction time; Kinetic hydrates; Thermodynamics and kinetics, Multiwalled carbon nanotubes (MWCN), carbon dioxide; carbon nanotube; concentration (composition); experimental study; gas hydrate; performance assessment; reaction kinetics; thermodynamics
note: cited By 37
abstract: In this work, the impact of functional group on the thermodynamics and kinetics of CO2 hydrates are investigated experimentally. The hydroxylated multi-wall carbon nanotubes (OH-MWCNT) and carboxylated carbon nanotubes (COOH-MWCNT) along with pristine carbon nanotubes (MWCNT) are selected for this study. The carbon nanotubes are suspended in a 0.03 wt sodium dodecyl sulfate (SDS) aqueous solution and the results are compared with SDS aqueous solution at the same concentration of 0.03 wt and deionized water. The CO2 hydrate phase boundary and kinetic parameters of CO2 hydrate formation including induction time, the initial rate and amount of gas consumed, gas uptake, storage capacity, and water to hydrates conversion are studied. The results show that the nanofluids studied do not affect the equilibrium conditions of CO2 hydrates. In addition, 0.01 and 0.05 wt of COOH-MWCNT mixed with 0.03 wt SDS showed highest initial hydrate formation rate and gas uptake. Furthermore, a comparison between SDS and COOH-MWCNT (without stabilizer SDS) at 0.03 wt revealed that addition of COOH-MWCNT to the water enhance the initial hydrates formation rate compared to SDS. © 2019 Elsevier Ltd
date: 2019
publisher: Elsevier Ltd
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85063113394&doi=10.1016%2fj.energy.2019.02.193&partnerID=40&md5=76b6ba41e3218c55bc815198669407f8
id_number: 10.1016/j.energy.2019.02.193
full_text_status: none
publication: Energy
volume: 174
pagerange: 602-610
refereed: TRUE
issn: 03605442
citation:   Nashed, O. and Partoon, B. and Lal, B. and Sabil, K.M. and Shariff, A.M.  (2019) Investigation of functionalized carbon nanotubes� performance on carbon dioxide hydrate formation.  Energy, 174.  pp. 602-610.  ISSN 03605442