eprintid: 11496 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/01/14/96 datestamp: 2023-11-10 03:26:00 lastmod: 2023-11-10 03:26:00 status_changed: 2023-11-10 01:15:24 type: article metadata_visibility: show creators_name: Tran, N.T.T. creators_name: Trinh, T.H. creators_name: Uemura, Y. creators_name: Ramli, A. title: A kinetic experiment of vapor phase hydrodeoxygenation of a bio-oil model compound over PdFe/Al-MCM-41 catalyst ispublished: pub note: cited By 2 abstract: The lignocellulose biomass resource can be used not only as direct energy in combustion, but also as a more valuable fuel after conversion and upgrading process. Fast pyrolysis is an approach that produces bio-oil from biomass. However, it is very difficult to directly utilize the pyrolysis oil because of the presence of oxygenated compounds (e.g., acids, esters, alcohols, ketones, furans and phenols). Hydrodeoxygenation (HDO) is a prominent process to upgrade bio-oil. The HDO experimental and kinetic study were conducted using PdFe/Al-MCM-41 catalyst in a tubular fixed-bed reactor. Kinetic model was proposed and applied to 21 reaction pathways, 13 compounds. The detailed reaction pathways of HDO of guaiacol and their reaction rates were clarified for a PdFe catalyst. The major pathway of HDO of guaiacol is direct production of phenol and then benzene. The detailed kinetic model is an effective tool to estimate the major reaction pathways of HDO process. ©BEIESP. date: 2019 publisher: Blue Eyes Intelligence Engineering and Sciences Publication official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85070760934&partnerID=40&md5=716ef5d9e67a80608e7906b047d900f5 full_text_status: none publication: International Journal of Recent Technology and Engineering volume: 8 number: 2 Spec pagerange: 597-601 refereed: TRUE issn: 22773878 citation: Tran, N.T.T. and Trinh, T.H. and Uemura, Y. and Ramli, A. (2019) A kinetic experiment of vapor phase hydrodeoxygenation of a bio-oil model compound over PdFe/Al-MCM-41 catalyst. International Journal of Recent Technology and Engineering, 8 (2 Spec). pp. 597-601. ISSN 22773878