eprintid: 11352
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/13/52
datestamp: 2023-11-10 03:25:52
lastmod: 2023-11-10 03:25:52
status_changed: 2023-11-10 01:15:03
type: article
metadata_visibility: show
creators_name: Nallappan, M.L.
creators_name: Nasef, M.M.
creators_name: Ting, T.M.
creators_name: Ahmad, A.
title: Breakthrough modelling of glucamine functionalized PVDF nanofibrous adsorbent in a fixed-bed column for separation of boron from water
ispublished: pub
keywords: adsorption; aqueous solution; boron; breakthrough curve; column; concentration (composition); modeling; reaction kinetics; separation; water quality
note: cited By 3
abstract: The performance of new nanofibrous chelating adsorbent, prepared by radiation induced grafting of glycidyl methacrylate onto electrospun poly(vinylidene fluoride) (PVDF) nanofibers followed by functionalization with N-methyl-D-glucamine, for removal of boron from aqueous solutions using a fixed-bed column was evaluated. The breakthrough curve was studied under various parameters including initial concentration, flow rate and bed height at pH 7. The column performance was evaluated with Yoon-Nelson and Thomas adsorption kinetic models. The maximum performance for boron adsorption was obtained at an initial concentration of 10 mg L-1, a space velocity (SV) of 15 h-1 and a room temperature of 28°C. The breakthrough capacity was found to be a function of both initial feed concentration and flow rate. Thomas model was found to best fit the dynamic behaviour of the column. The newly obtained adsorbent was proven to be capable of removing boron efficiently from aqueous solutions in continuous fixed-bed systems at high flow rates and has potential for industrial-scale application. © 2019 Desalination Publications.
date: 2019
publisher: Desalination Publications
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85072051002&doi=10.5004%2fdwt.2019.24329&partnerID=40&md5=a51101aa8fc081423347619c2c5a030f
id_number: 10.5004/dwt.2019.24329
full_text_status: none
publication: Desalination and Water Treatment
volume: 162
pagerange: 134-141
refereed: TRUE
issn: 19443994
citation:   Nallappan, M.L. and Nasef, M.M. and Ting, T.M. and Ahmad, A.  (2019) Breakthrough modelling of glucamine functionalized PVDF nanofibrous adsorbent in a fixed-bed column for separation of boron from water.  Desalination and Water Treatment, 162.  pp. 134-141.  ISSN 19443994