eprintid: 11216
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/12/16
datestamp: 2023-11-10 03:25:44
lastmod: 2023-11-10 03:25:44
status_changed: 2023-11-10 01:14:44
type: article
metadata_visibility: show
creators_name: Rasdi, F.L.M.
creators_name: Rahim, N.Y.
creators_name: Hasim, F.W.
creators_name: Prabu, S.
creators_name: Jumbri, K.
creators_name: Manan, N.S.A.
creators_name: Mohamad, S.
title: Influence of degree of substitution on the host-guest inclusion complex between ionic liquid substituted β-cyclodextrins with 2,4-dichlorophenol: An electrochemical, NMR and molecular docking studies
ispublished: pub
keywords: Cyclodextrins; Electrodes; Ionic liquids; Molecular modeling, 4-dichlorophenol; Carbon paste electrode; Inclusion complex; Molecular docking; NOESY analysis, Cyclic voltammetry
note: cited By 5
abstract: A mono- and di-substituted ionic liquid-β-cyclodextrin (β-CD-ILs) were synthesized and their host-guest inclusion complex with 2, 4-dichlorophenol (2,4-DCP) were evaluated by electrochemical study. First, both β-CD-ILs which is β-CD-1-BIMOTs and β-CD-2-BIMOTs were fabricated on carbon paste electrode (CPE) for determination of 2,4-DCP. The cyclic voltammetry results indicate that both β-CD-IL/CPEs exhibit higher oxidation peak current compared to native β-CD/CPE. Both complexes possess high sensitivity, stability and reproducibility. However, as the degree of substitution of ionic liquid (IL) increases, the selectivity of β-CD-IL towards 2,4-DCP decreases. Thus, it can be deduced that the degree of substitution of IL is influencing the host-guest inclusion complex of β-CD-ILs with 2,4-DCP. © 2019 Elsevier B.V.
date: 2019
publisher: Elsevier B.V.
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85069693065&doi=10.1016%2fj.molliq.2019.111334&partnerID=40&md5=89dc9a3067a15f958c04ebf60bc3ff1c
id_number: 10.1016/j.molliq.2019.111334
full_text_status: none
publication: Journal of Molecular Liquids
volume: 292
refereed: TRUE
issn: 01677322
citation:   Rasdi, F.L.M. and Rahim, N.Y. and Hasim, F.W. and Prabu, S. and Jumbri, K. and Manan, N.S.A. and Mohamad, S.  (2019) Influence of degree of substitution on the host-guest inclusion complex between ionic liquid substituted β-cyclodextrins with 2,4-dichlorophenol: An electrochemical, NMR and molecular docking studies.  Journal of Molecular Liquids, 292.   ISSN 01677322