relation: https://khub.utp.edu.my/scholars/11216/
title: Influence of degree of substitution on the host-guest inclusion complex between ionic liquid substituted β-cyclodextrins with 2,4-dichlorophenol: An electrochemical, NMR and molecular docking studies
creator: Rasdi, F.L.M.
creator: Rahim, N.Y.
creator: Hasim, F.W.
creator: Prabu, S.
creator: Jumbri, K.
creator: Manan, N.S.A.
creator: Mohamad, S.
description: A mono- and di-substituted ionic liquid-β-cyclodextrin (β-CD-ILs) were synthesized and their host-guest inclusion complex with 2, 4-dichlorophenol (2,4-DCP) were evaluated by electrochemical study. First, both β-CD-ILs which is β-CD-1-BIMOTs and β-CD-2-BIMOTs were fabricated on carbon paste electrode (CPE) for determination of 2,4-DCP. The cyclic voltammetry results indicate that both β-CD-IL/CPEs exhibit higher oxidation peak current compared to native β-CD/CPE. Both complexes possess high sensitivity, stability and reproducibility. However, as the degree of substitution of ionic liquid (IL) increases, the selectivity of β-CD-IL towards 2,4-DCP decreases. Thus, it can be deduced that the degree of substitution of IL is influencing the host-guest inclusion complex of β-CD-ILs with 2,4-DCP. © 2019 Elsevier B.V.
publisher: Elsevier B.V.
date: 2019
type: Article
type: PeerReviewed
identifier:   Rasdi, F.L.M. and Rahim, N.Y. and Hasim, F.W. and Prabu, S. and Jumbri, K. and Manan, N.S.A. and Mohamad, S.  (2019) Influence of degree of substitution on the host-guest inclusion complex between ionic liquid substituted β-cyclodextrins with 2,4-dichlorophenol: An electrochemical, NMR and molecular docking studies.  Journal of Molecular Liquids, 292.   ISSN 01677322     
relation: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85069693065&doi=10.1016%2fj.molliq.2019.111334&partnerID=40&md5=89dc9a3067a15f958c04ebf60bc3ff1c
relation: 10.1016/j.molliq.2019.111334
identifier: 10.1016/j.molliq.2019.111334