<> "The repository administrator has not yet configured an RDF license."^^ . <> . . . "Synthesis, and characterization of metal-organic frameworks -177 for static and dynamic adsorption behavior of CO2 and CH4"^^ . "In this work, a microporous metal organic framework (MOF-177) was synthesized and characterized to investigate the static and dynamic adsorption behavior of CO2 and CH4. The synthesized MOF-177 was found to be six-dimensional shaped channels with an average pore diameter of 1.18 nm. The characterization of synthesized MOF-177 involves the FESEM, powder XRD, FT-IR, TGA/DTG, and BET with nitrogen adsorption. The FESEM images disclosed the distinct crystals with needles type geometrical shape containing large pore with diameter in the range of 20.15 à . The surface area of MOF-177 was found to be 1721 m2/g with CO2 adsorption capacity of 1.03 mmol/g and CO2/CH4 equilibrium selectivity of 3.21 at ambient conditions i.e. 1 atm and 25 °C. MOF-177 found to be in remarkable regeneration ability by sustaining its CO2 adsorption capacity over several adsorption-desorption cycles. Dynamic separation of binary mixture with compositions (CO2:CH4 30:70 and CO2:CH4 70:30) through a fixed bed column revealed that the CH4 pass through the MOF-177 faster than CO2 indicating the higher selectivity for CO2 compared to CH4. Finally, MOF-177 still hold great promise in CO2 separation from natural gas provided it is protected from moisture. © 2019 Elsevier Inc."^^ . "2019" . . "288" . . "Elsevier B.V."^^ . . . "Microporous and Mesoporous Materials"^^ . . . "13871811" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . "A."^^ . "Mukhtar"^^ . "A. Mukhtar"^^ . . "M.A."^^ . "Bustam"^^ . "M.A. Bustam"^^ . . "S."^^ . "Ullah"^^ . "S. Ullah"^^ . . "A.G."^^ . "Al-Sehemi"^^ . "A.G. Al-Sehemi"^^ . . "G."^^ . "Gonfa"^^ . "G. Gonfa"^^ . . "M.A."^^ . "Assiri"^^ . "M.A. Assiri"^^ . . "A.E.I."^^ . "Elkhalifah"^^ . "A.E.I. Elkhalifah"^^ . . "M."^^ . "Sagir"^^ . "M. Sagir"^^ . . "F.A."^^ . "Abdul Kareem"^^ . "F.A. Abdul Kareem"^^ . . . . . "HTML Summary of #11198 \n\nSynthesis, and characterization of metal-organic frameworks -177 for static and dynamic adsorption behavior of CO2 and CH4\n\n" . "text/html" . .