TY  - JOUR
UR  - https://www.scopus.com/inward/record.uri?eid=2-s2.0-85068258196&doi=10.1016%2fj.radphyschem.2019.108375&partnerID=40&md5=f23518013e2b02b067952629d2dd2e6d
JF  - Radiation Physics and Chemistry
A1  - Moawia, R.M.
A1  - Nasef, M.M.
A1  - Mohamed, N.H.
A1  - Ripin, A.
A1  - Zakeri, M.
VL  - 164
Y1  - 2019///
SN  - 0969806X
PB  - Elsevier Ltd
N2  - A biopolymer-based catalyst with an alkaline moiety was prepared by radiation induced grafting (RIG) of glycidylmethaacrylate (GMA) onto flax fibres followed by functionalisation with diethyl amine (DEA) and treatment with NaOH. The density of amine loading was tuned by optimisation of the reaction parameters including DEA concentration, reaction temperature, and time using the Boxâ??Behnken Design (BBD) of Response Surface Methodology (RSM). The chemical composition, morphology and structure of the alkaline catalyst were examined using Fourier-transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM) and X-ray diffraction (XRD), respectively. Thermal properties of the catalyst were examined by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The optimum parameters for obtaining a maximum amine density (3.65 mmol/g) in the catalyst were 79.8 DEA concentration, 80 °C reaction temperature, and 2.9 h reaction time. The catalyst was tested for transesterification of cottonseed oil with methanol. A maximum 88.6 conversion to fatty acid methyl ester (FAME) was achieved at optimum parameters of 33:1 methanol/oil molar ratio, 2.5 wt catalyst concentration and 60 °C reaction temperature. The results indicate that radiation induced grafting can be effectively used to prepare alkaline biocatalyst catalyst from flax fibres and the catalyst is a promising green candidate for biodiesel production. © 2019 Elsevier Ltd
N1  - cited By 11
KW  - Acrylic monomers; Alkalinity; Biodiesel; Biomolecules; Cottonseed oil; Differential scanning calorimetry; Ethanolamines; Fatty acids; Flax; Fourier transform infrared spectroscopy; Grafting (chemical); Linen; Methanol; Molar concentration; Molar ratio; Morphology; Scanning electron microscopy; Sodium hydroxide; Surface properties; Thermogravimetric analysis; Yarn
KW  -  Biodiesel production; Diethylamines; Fatty acid methyl ester; Fourier transform infra red (FTIR) spectroscopy; Morphology and structures; Poly(glycidyl methacrylate); Radiation-induced grafting; Response surface methodology
KW  -  Biocatalysts
KW  -  amine; biodiesel; biopolymer; cotton seed oil; diethylamine; fatty acid ester; glycidyl methacrylate; methacrylic acid; methanol; sodium hydroxide; unclassified drug
KW  -  alkalinity; analytic method; Article; biofuel production; catalyst; chemical composition; chemical structure; concentration (parameter); differential scanning calorimetry; Fourier transform infrared spectroscopy; process optimization; reaction duration (chemistry); reaction temperature; response surface method; scanning electron microscopy; thermogravimetry; transesterification; X ray diffraction
ID  - scholars11197
TI  - Biopolymer catalyst for biodiesel production by functionalisation of radiation grafted flax fibres with diethylamine under optimised conditions
AV  - none
ER  -