TY - JOUR KW - Actinium; Activated carbon; Adsorption; Chlorine compounds; Fourier transform infrared spectroscopy; Gravimetric analysis; Oxidation; Salicylic acid; Scanning electron microscopy; Sodium compounds; Surface treatment; Thermogravimetric analysis; Water pollution KW - Batch adsorption experiments; Carbonaceous sorbents; Modified adsorbents; Multiwalled carbon nanotube (MWCNTs); MWCNTs; Oxidizing agents; Surface area analyzers; Thermal gravimetric analyses (TGA) KW - Multiwalled carbon nanotubes (MWCN) KW - activated carbon; adsorbent; benzene; citric acid; malic acid; multi walled nanotube; oil; oxidizing agent; salicylic acid; tartaric acid; toluene; xylene KW - activated carbon; adsorption; aqueous solution; carbon nanotube; chemical pollutant; organic acid; pollutant removal; surface area KW - adsorption; aqueous solution; Article; chemical modification; concentration (parameter); field emission scanning electron microscopy; Fourier transform infrared spectroscopy; pore volume; Raman spectrometry; surface area; surface property; thermogravimetry; thermostability; titrimetry; waste component removal; water pollution control; X ray diffraction; zeta potential N1 - cited By 15 Y1 - 2019/// A1 - Anjum, H. A1 - Johari, K. A1 - Appusamy, A. A1 - Gnanasundaram, N. A1 - Thanabalan, M. ID - scholars11115 SN - 03043894 TI - Surface modification and characterization of carbonaceous adsorbents for the efficient removal of oil pollutants AV - none UR - https://www.scopus.com/inward/record.uri?eid=2-s2.0-85067863800&doi=10.1016%2fj.jhazmat.2019.05.066&partnerID=40&md5=ea9f6aafccb77de202923168b3f81b00 JF - Journal of Hazardous Materials VL - 379 N2 - In this study, the impact of different oxidizing agents on the structural integrity of activated carbon (AC) and multiwalled carbon nanotubes (MWCNTs) was studied for the removal of BTX from aqueous solution. Seven different combinations of green oxidizing agents (mild organic acids) in conjugation with NaOCl (basic oxidizing agent) were used. The modified adsorbents were analyzed by Brunauer, Emmett, and Teller (BET) surface area analyzer, Fourier transform infrared spectroscopy (FTIR), Boehm titration, Raman spectroscopy, thermal gravimetric analysis (TGA), x-ray diffraction (XRD), zeta potential, and variable pressure field emission scanning electron microscope (VPFESEM). The results suggested that the carbonaceous sorbents modified with combination of citric acid tartaric acid, malic acid and salicylic acid (CTMS-I) showed increased surface area (O-AC: 871.67 m2/g, O-MWCNTs: 336.37 m2/g) and total pore volume (O-AC: 0.59 cm3/g, O-MWCNTs: 0.04 cm3/g), with the significantly improved thermal stability. Preliminary batch adsorption experiments conducted using the present prepared O-AC and O-MWCNTs, showed an improved performance towards the adsorption of BTX, compared with other available reported adsorbents in the literature. © 2019 Elsevier B.V. PB - Elsevier B.V. ER -