eprintid: 11090
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/10/90
datestamp: 2023-11-10 03:25:38
lastmod: 2023-11-10 03:25:38
status_changed: 2023-11-10 01:14:28
type: article
metadata_visibility: show
creators_name: Rashid, Z.
creators_name: Wilfred, C.D.
creators_name: Iyyaswami, R.
creators_name: Appusamy, A.
creators_name: Thanabalan, M.
title: Investigating the solubility of petroleum asphaltene in ionic liquids and their interaction using COSMO-RS
ispublished: pub
keywords: Dispersion (waves); Dispersions; Ionic liquids; Molecules; Negative ions; Petroleum transportation; Solubility, Conductor-like screening model for real solvents; COSMO-RS; Hydrophobic anions; Imidazolium-based; Ionic liquid (ils); Petroleum asphaltenes; Structural variations; Transportation process, Asphaltenes
note: cited By 20
abstract: Dispersion of asphaltene in crude oil using ionic liquids (ILs) is being considered as a viable solution, in extraction and transportation processes. In this work, the interplay between asphaltene and ILs has been studied systematically to understand the effect of structural variation of ILs on asphaltene solubility. The activity coefficient of the total of 1517 ILs with different combinations of cation and anion of ILs for representative asphaltene molecule (asphaltene) was estimated via COSMO-RS (Conductor-like Screening Model for Real Solvents). COSMORS predictions were validated using experimental data on asphaltene solubility. Among the studied ILs, asphaltene showed high solubility in imidazolium-based ILs with hydrophobic anions. The present approach paved a way forward to rationally understand the impact of structural variation of ILs on their interaction with asphaltene molecule and to design new ILs for the dispersion and stabilization of asphaltene. © 2019 The Korean Society of Industrial and Engineering Chemistry
date: 2019
publisher: Korean Society of Industrial Engineering Chemistry
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85069734016&doi=10.1016%2fj.jiec.2019.06.034&partnerID=40&md5=1e05e4c140295a7b9dfa49122b120164
id_number: 10.1016/j.jiec.2019.06.034
full_text_status: none
publication: Journal of Industrial and Engineering Chemistry
volume: 79
pagerange: 194-203
refereed: TRUE
issn: 1226086X
citation:   Rashid, Z. and Wilfred, C.D. and Iyyaswami, R. and Appusamy, A. and Thanabalan, M.  (2019) Investigating the solubility of petroleum asphaltene in ionic liquids and their interaction using COSMO-RS.  Journal of Industrial and Engineering Chemistry, 79.  pp. 194-203.  ISSN 1226086X