TY  - JOUR
VL  - 79
AV  - none
KW  - Dispersion (waves); Dispersions; Ionic liquids; Molecules; Negative ions; Petroleum transportation; Solubility
KW  -  Conductor-like screening model for real solvents; COSMO-RS; Hydrophobic anions; Imidazolium-based; Ionic liquid (ils); Petroleum asphaltenes; Structural variations; Transportation process
KW  -  Asphaltenes
N2  - Dispersion of asphaltene in crude oil using ionic liquids (ILs) is being considered as a viable solution, in extraction and transportation processes. In this work, the interplay between asphaltene and ILs has been studied systematically to understand the effect of structural variation of ILs on asphaltene solubility. The activity coefficient of the total of 1517 ILs with different combinations of cation and anion of ILs for representative asphaltene molecule (asphaltene) was estimated via COSMO-RS (Conductor-like Screening Model for Real Solvents). COSMORS predictions were validated using experimental data on asphaltene solubility. Among the studied ILs, asphaltene showed high solubility in imidazolium-based ILs with hydrophobic anions. The present approach paved a way forward to rationally understand the impact of structural variation of ILs on their interaction with asphaltene molecule and to design new ILs for the dispersion and stabilization of asphaltene. © 2019 The Korean Society of Industrial and Engineering Chemistry
ID  - scholars11090
Y1  - 2019///
N1  - cited By 20
EP  - 203
TI  - Investigating the solubility of petroleum asphaltene in ionic liquids and their interaction using COSMO-RS
JF  - Journal of Industrial and Engineering Chemistry
PB  - Korean Society of Industrial Engineering Chemistry
A1  - Rashid, Z.
A1  - Wilfred, C.D.
A1  - Iyyaswami, R.
A1  - Appusamy, A.
A1  - Thanabalan, M.
UR  - https://www.scopus.com/inward/record.uri?eid=2-s2.0-85069734016&doi=10.1016%2fj.jiec.2019.06.034&partnerID=40&md5=1e05e4c140295a7b9dfa49122b120164
SP  - 194
SN  - 1226086X
ER  -