<> "The repository administrator has not yet configured an RDF license."^^ . <> . . . "Synthesis and characterization of iso-reticular metal-organic Framework-3 (IRMOF-3) for CO2/CH4 adsorption: Impact of post-synthetic aminomethyl propanol (AMP) functionalization"^^ . "In this study, an iso-reticular metal-organic framework-3(IRMOF-3) exhibiting microporosity was synthesized from organic linker 2-amino terephthalic acid and salt zinc nitrate hexahydrate (Zn-(NO3)2.6H2O) via catalyst-free, solution-based direct mixing technique. Three samples of IRMOF-3 were post-synthetically functionalized with aminomethyl propanol (AMP) with three different concentrations of 25 wt, 50 wt and 75 wt to produce AMP@IRMOF-3. The structural and texture properties of AMP@IRMOF-3 were studied by FESEM, FTIR, pore size distribution, powder XRD, TGA/DTG, N2 adsorption-desorption isotherms, their selective CO2/CH4 adsorption behaviour over various temperatures (298.15 K, 323.15 K, and 348.15 K). The results showed an enhancement in CO2 adsorption capacity from 1.39 mmol/g to 3.90 mmol/g due to successful incorporation of CO2 philic functionalities. Furthermore, the adsorption isotherms were studied by applying Langmuir, Freundlich, Langmuir-Freundlich, and Toth isotherm models. The isotherms study revealed the unfavourable adsorption behaviour with an increase in AMP loadings with a homogenous system. © 2019 Elsevier B.V."^^ . "2019" . . "72" . . "Elsevier B.V."^^ . . . "Journal of Natural Gas Science and Engineering"^^ . . . "18755100" . . . . . . . . . . . . . . . . . . . . . . . . . . . . "G."^^ . "Gonfa"^^ . "G. Gonfa"^^ . . "M.A."^^ . "Bustam"^^ . "M.A. Bustam"^^ . . "S."^^ . "Ullah"^^ . "S. Ullah"^^ . . "F.A."^^ . "Abdul Kareem"^^ . "F.A. Abdul Kareem"^^ . . "A.G."^^ . "Al-Sehemi"^^ . "A.G. Al-Sehemi"^^ . . "A."^^ . "Mukhtar"^^ . "A. Mukhtar"^^ . . "M."^^ . "Ayoub"^^ . "M. Ayoub"^^ . . "M.A."^^ . "Assiri"^^ . "M.A. Assiri"^^ . . . . . "HTML Summary of #11049 \n\nSynthesis and characterization of iso-reticular metal-organic Framework-3 (IRMOF-3) for CO2/CH4 adsorption: Impact of post-synthetic aminomethyl propanol (AMP) functionalization\n\n" . "text/html" . .