eprintid: 10902
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/09/02
datestamp: 2023-11-09 16:37:31
lastmod: 2023-11-09 16:37:31
status_changed: 2023-11-09 16:32:28
type: article
metadata_visibility: show
creators_name: Shaharun, S.
creators_name: Shaharun, M.S.
creators_name: Shah, M.F.M.
creators_name: Amer, N.A.
title: Catalytic performance of Cu/ZnO/Al2O3/ZrO2 for slurry methanol synthesis from CO hydrogenation: Effect of Cu/Zn molar ratio
ispublished: pub
keywords: aluminum oxide; carbon dioxide; catalyst; copper; hydrogen; methanol; slurry; zinc; zirconium
note: cited By 1
abstract: Catalytic hydrogenation of carbon dioxide (CO2) to methanol is an attractive way to recycle and utilize CO2. A series of Cu/ZnO/Al2O3/ZrO2 catalysts (CZAZ) containing different molar ratios of Cu/Zn were prepared by the co-precipitation method. The catalysts were characterized by temperature-programmed reduction (TPR), field emission scanning electron microscopy-energy dispersive x-ray analysis (FESEM-EDX) and X-ray diffraction (XRD). Higher surface area, SABET values (42.6-59.9 m2/g) were recorded at low (1) and high (5) Cu/Zn ratios with the minimum value of 35.71 m2/g was found for a Cu/Zn of 3. The reducibility of the metal oxides formed after calcination of catalyst samples was also affected due to change in metal-support interaction. At a reaction temperature of 443 K, total gas pressure of 3.0 MPa and 0.1 g/ mL of the CZAZ catalyst, the selectivity to methanol decreased as the Cu/Zn molar ratio increased, and the maximum selectivity of 93.9 was achieved at Cu/Zn molar ratio of 0.33. With a reaction time of 3h, the best performing catalyst was CZAZ75 with Cu/Zn molar ratio of 5 giving methanol yield of 6.4.
date: 2018
publisher: Penerbit Universiti Kebangsaan Malaysia
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85041930035&doi=10.17576%2fjsm-2018-4701-24&partnerID=40&md5=62163667cfe50e70c41b2267cf68cc5d
id_number: 10.17576/jsm-2018-4701-24
full_text_status: none
publication: Sains Malaysiana
volume: 47
number: 1
pagerange: 207-214
refereed: TRUE
issn: 01266039
citation:   Shaharun, S. and Shaharun, M.S. and Shah, M.F.M. and Amer, N.A.  (2018) Catalytic performance of Cu/ZnO/Al2O3/ZrO2 for slurry methanol synthesis from CO hydrogenation: Effect of Cu/Zn molar ratio.  Sains Malaysiana, 47 (1).  pp. 207-214.  ISSN 01266039