@article{scholars10902,
           title = {Catalytic performance of Cu/ZnO/Al2O3/ZrO2 for slurry methanol synthesis from CO hydrogenation: Effect of Cu/Zn molar ratio},
             doi = {10.17576/jsm-2018-4701-24},
          volume = {47},
            note = {cited By 1},
          number = {1},
           pages = {207--214},
       publisher = {Penerbit Universiti Kebangsaan Malaysia},
         journal = {Sains Malaysiana},
            year = {2018},
          author = {Shaharun, S. and Shaharun, M. S. and Shah, M. F. M. and Amer, N. A.},
            issn = {01266039},
             url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85041930035&doi=10.17576\%2fjsm-2018-4701-24&partnerID=40&md5=62163667cfe50e70c41b2267cf68cc5d},
        keywords = {aluminum oxide; carbon dioxide; catalyst; copper; hydrogen; methanol; slurry; zinc; zirconium},
        abstract = {Catalytic hydrogenation of carbon dioxide (CO2) to methanol is an attractive way to recycle and utilize CO2. A series of Cu/ZnO/Al2O3/ZrO2 catalysts (CZAZ) containing different molar ratios of Cu/Zn were prepared by the co-precipitation method. The catalysts were characterized by temperature-programmed reduction (TPR), field emission scanning electron microscopy-energy dispersive x-ray analysis (FESEM-EDX) and X-ray diffraction (XRD). Higher surface area, SABET values (42.6-59.9 m2/g) were recorded at low (1) and high (5) Cu/Zn ratios with the minimum value of 35.71 m2/g was found for a Cu/Zn of 3. The reducibility of the metal oxides formed after calcination of catalyst samples was also affected due to change in metal-support interaction. At a reaction temperature of 443 K, total gas pressure of 3.0 MPa and 0.1 g/ mL of the CZAZ catalyst, the selectivity to methanol decreased as the Cu/Zn molar ratio increased, and the maximum selectivity of 93.9 was achieved at Cu/Zn molar ratio of 0.33. With a reaction time of 3h, the best performing catalyst was CZAZ75 with Cu/Zn molar ratio of 5 giving methanol yield of 6.4.}
}