eprintid: 10550
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/05/50
datestamp: 2023-11-09 16:37:10
lastmod: 2023-11-09 16:37:10
status_changed: 2023-11-09 16:31:40
type: article
metadata_visibility: show
creators_name: Bavoh, C.B.
creators_name: Nashed, O.
creators_name: Khan, M.S.
creators_name: Partoon, B.
creators_name: Lal, B.
creators_name: Sharif, A.M.
title: The impact of amino acids on methane hydrate phase boundary and formation kinetics
ispublished: pub
keywords: Amino acids; Enzyme kinetics; Hydration; Kinetics; Methane; Phase boundaries, Dissociation temperature; Equilibrium phase; Formation kinetics; Hydrate formation; Inhibition effect; Kinetic effect; Mass fraction; Methane hydrates, Gas hydrates
note: cited By 94
abstract: The thermodynamic and kinetic effects of two amino acids (valine and arginine) on methane hydrate formation was evaluated by measuring the dissociation temperature of methane hydrate in the range of 4.5�10 MPa using the T-cycle method. The kinetics of methane hydrate formation was evaluated at 7.1 MPa and 274.15 K. The experiments were conducted at concentrations of 0.01 and 0.05 mass fraction. Both amino acids showed a slight inhibition effect on the phase boundary of methane hydrate. The predicted methane hydrate phase boundary data in the presence of amino acids was strongly correlated with the experimental data with R = 0.9996 and an AAE less than 0.15 K. However, these amino acids also showed hydrate formation rate enhancement compared to pure water. In addition, the total methane uptake at the end of the experiments was increased in the presence of these amino acids. © 2017 Elsevier Ltd
date: 2018
publisher: Academic Press
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85029215093&doi=10.1016%2fj.jct.2017.09.001&partnerID=40&md5=26af52c911b1229f5b874ad0c81780c7
id_number: 10.1016/j.jct.2017.09.001
full_text_status: none
publication: Journal of Chemical Thermodynamics
volume: 117
pagerange: 48-53
refereed: TRUE
issn: 00219614
citation:   Bavoh, C.B. and Nashed, O. and Khan, M.S. and Partoon, B. and Lal, B. and Sharif, A.M.  (2018) The impact of amino acids on methane hydrate phase boundary and formation kinetics.  Journal of Chemical Thermodynamics, 117.  pp. 48-53.  ISSN 00219614