relation: https://khub.utp.edu.my/scholars/10342/
title: Photoelectrochemical water splitting with tailored TiO2/SrTiO3@g-C3N4 heterostructure nanorod in photoelectrochemical cell
creator: Bashiri, R.
creator: Mohamed, N.M.
creator: Suhaimi, N.A.
creator: Shahid, M.U.
creator: Kait, C.F.
creator: Sufian, S.
creator: Khatani, M.
creator: Mumtaz, A.
description: Solar hydrogen production through water photosplitting in photoelectrochemical (PEC) cell is one of the most desirable, cost-effective and environmentally friendly processes. However, it is still suffering from the low photoconversion efficiency. A novel tailored TiO2/SrTiO3@g-C3N4 heterostructure nanorod was synthesized to investigate the photocatalytic hydrogen production under visible light condition in glycerol-based PEC cell. A series of TiO2 and TiO2/SrTiO3 nanorod were grown on F-doped SnO2 glass (FTO) substrate by hydrothermal method and then were modified using graphitic carbon nitride g-C3N4 via the chemical bath deposition technique. The samples were characterized using X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HRTEM), diffuse reflectance UV�Vis spectroscopy (DR-UV�Vis), and Fourier transform infrared (FTIR) to explore the physicochemical properties of the prepared photocatalysts. The prepared TiO2/SrTiO3@g-C3N4 served as the efficient photoanode with maximum produced hydrogen of 73 μmol/cm2 compared to others. This photocatalyst had more uniformed structures and shifted more absorbance to the visible region as presented in FESEM and DR-UV�Vis. Therefore, high performance of this photocatalyst can be ascribed to the close interfacial connections between g-C3N4 and TiO2/SrTiO3 where the photo-generated electron and holes were effectively separated. © 2018 Elsevier B.V.
publisher: Elsevier Ltd
date: 2018
type: Article
type: PeerReviewed
identifier:   Bashiri, R. and Mohamed, N.M. and Suhaimi, N.A. and Shahid, M.U. and Kait, C.F. and Sufian, S. and Khatani, M. and Mumtaz, A.  (2018) Photoelectrochemical water splitting with tailored TiO2/SrTiO3@g-C3N4 heterostructure nanorod in photoelectrochemical cell.  Diamond and Related Materials, 85.  pp. 5-12.  ISSN 09259635     
relation: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85044481723&doi=10.1016%2fj.diamond.2018.03.019&partnerID=40&md5=e4ec2a23845887568bd4c94cd09a6d34
relation: 10.1016/j.diamond.2018.03.019
identifier: 10.1016/j.diamond.2018.03.019