eprintid: 10059 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/01/00/59 datestamp: 2023-11-09 16:36:41 lastmod: 2023-11-09 16:36:41 status_changed: 2023-11-09 16:30:29 type: article metadata_visibility: show creators_name: Khan, Z. creators_name: Yusup, S. creators_name: Ahmad, M.M. creators_name: Inayat, A. creators_name: Naqvi, M. creators_name: Sheikh, R. creators_name: Watson, I. title: Integrated catalytic adsorption steam gasification in a bubbling fluidized bed for enhanced H2 production: perspective of design and pilot plant experiences ispublished: pub keywords: Adsorption; Bubble formation; Carbon dioxide; Catalyst activity; Chemical shift; Fluidized bed process; Gasification; Hydrogen; Hydrogen production; Palm oil; Pilot plants; Steam; Steam reforming; Water gas shift, Bubbling fluidized bed; Enhanced hydrogen productions; Palm kernel shells; Performance evaluations; Pilot plant operations; Steam gasification; Temperature variation; Water gas shift (WGS) reaction, Fluidized beds note: cited By 3 abstract: It is important to build knowledge about the design of an integrated catalytic adsorption (ICA) steam gasification process in a bubbling fluidized bed, which can reduce CO2 content with enhanced hydrogen production. The value of this study is its presentation of detailed design considerations for the performance evaluation of an ICA system using palm oil waste as feedstock. The main advantage of using ICA gasification systems is the CO2 adsorption through a carbonation reaction (using CaO), which helps the water gas shift reaction to move forward. The activity of a catalyst improves steam methane reforming in parallel, which not only produces additional hydrogen but also releases CO to enhance the activity of the water gas shift reaction. The performance of the developed system has shown <1 of temperature variation inside the reactor, which suggested a positive role for exothermic reactions between reactive bed material (CaO) and CO2 in the product gas. The low pressure drop in the gasifier (100�130 mbar) further strengthens the design strategy for the ICA gasification system for hydrogen production. Challenges encountered during the pilot plant operations, and their potential solutions, are discussed to optimize the operation, especially for downstream equipment and auxiliaries. © 2018 Society of Chemical Industry and John Wiley & Sons, Ltd. © 2018 Society of Chemical Industry and John Wiley & Sons, Ltd date: 2018 publisher: John Wiley and Sons Ltd official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85047517446&doi=10.1002%2fbbb.1885&partnerID=40&md5=31e0836a6c3b4cd72d07bc13f6e561e1 id_number: 10.1002/bbb.1885 full_text_status: none publication: Biofuels, Bioproducts and Biorefining volume: 12 number: 5 pagerange: 735-748 refereed: TRUE issn: 1932104X citation: Khan, Z. and Yusup, S. and Ahmad, M.M. and Inayat, A. and Naqvi, M. and Sheikh, R. and Watson, I. (2018) Integrated catalytic adsorption steam gasification in a bubbling fluidized bed for enhanced H2 production: perspective of design and pilot plant experiences. Biofuels, Bioproducts and Biorefining, 12 (5). pp. 735-748. ISSN 1932104X