@article{scholars10051, year = {2018}, pages = {106--112}, publisher = {Elsevier Ltd}, journal = {Biomass and Bioenergy}, doi = {10.1016/j.biombioe.2018.06.009}, volume = {116}, note = {cited By 17}, title = {Extraction of palm kernel shell derived pyrolysis oil by supercritical carbon dioxide: Evaluation and modeling of phenol solubility}, keywords = {Carbon dioxide; Lutetium; Models; Palm oil; Phenols; Pyrolysis; Solubility, Bio oil; Extraction yield; Model parameters; Palm kernel shells; Phenolic compounds; Supercritical carbon dioxides; Supercritical CO2 extraction; Value-added chemicals, Supercritical fluid extraction, carbon dioxide; extraction method; modeling; monocotyledon; oil; phenol; pressure; pyrolysis; shell; solubility; temperature; valuation}, url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85048734180&doi=10.1016\%2fj.biombioe.2018.06.009&partnerID=40&md5=403c9e77cecbd3c51f63903f6ebf488f}, abstract = {The extraction and recovery of value-added chemical compounds, such as phenolic compounds present in bio-oil has been a vital subject of study recently. In this work, the extraction of bio-oil using supercritical carbon dioxide (sc-CO2) with particular interest in apparent solubility of phenol (a major chemical compound in pyrolysis oil) was evaluated at various temperatures (50, 60 and 70 {\^A}oC) and pressures (30, 35 and 40 MPa). Highest extraction yield of bio-oil was obtained at 70 {\^A}oC and 40 MPa. The phenol content in the extracted bio-oils were also studied and reported. As a preliminary study, the apparent solubility data of phenol in sc-CO2 was successfully modeled using the values from the correlation of Chrastil, Adachi \& Lu and Bartle models. The model parameters for these equations were determined and reported in this work. It was found that Chrastil, Adachi \& Lu and Bartle models produced satisfactory correlations on the solubility of phenol in sc-CO2, with AARD values of 1.51, 6.52 and 1.85, respectively. {\^A}{\copyright} 2018 Elsevier Ltd}, issn = {09619534}, author = {Chan, Y. H. and Yusup, S. and Quitain, A. T. and Chai, Y. H. and Uemura, Y. and Loh, S. K.} }