Fractionation of pyrolysis oil via supercritical carbon dioxide extraction: Optimization study using response surface methodology (RSM)

Chan, Y.H. and Yusup, S. and Quitain, A.T. and Uemura, Y. and Loh, S.K. (2017) Fractionation of pyrolysis oil via supercritical carbon dioxide extraction: Optimization study using response surface methodology (RSM). Biomass and Bioenergy, 107. pp. 155-163. ISSN 09619534

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Abstract

The extraction of bio-oil produced from pyrolysis of palm kernel shell (PKS) using supercritical carbon dioxide (sc-CO2) was systematically studied using Response Surface Methodology (RSM) and optimized. Three parameters which included temperature (40-60 °C), pressure (20-35 MPa) and CO2 flowrate (3-8 cm3 min�1) were optimized for maximum extraction yield. The predicted optimum extraction condition at 48.0 °C, 28.2 MPa, 8.0 cm3 min�1 CO2 flowrate for maximum predicted extract yield of 30.03 (±2.65) was validated with experimental extract yield of 27.63 (±1.00). The regression model developed provided accurate predictions of the extract yield, with coefficient of determination R2 of 0.9501. The bio-oil extract obtained was then characterized by GC/MS, proximate, and ultimate analyses and compared with the raw bio-oil. Acids and esters were found to be enriched in the supercritical extract, while other classes of chemical compounds such as phenolics, aromatics, ketones and nitrogen compounds were also detected in the bio-oil extract. The interactive effects of process parameters on the extraction efficiency of sc-CO2 and the quality of bio-oil extract obtained were presented and discussed. © 2017

Item Type: Article
Additional Information: cited By 25
Uncontrolled Keywords: Biofuels; Carbon dioxide; Chemical analysis; Chemical compounds; Fractionation; Ketones; Nitrogen compounds; Palm oil; Pyrolysis; Regression analysis; Supercritical fluid extraction; Surface properties, Coefficient of determination; Extraction efficiencies; Optimization studies; Optimum extraction conditions; Palm kernel shells; Response surface methodology; Supercritical carbon dioxide extraction; Supercritical carbon dioxides, Extraction, biofuel; carbon dioxide; ester; extraction method; fractionation; parameterization; plant extract; pyrolysis; response surface methodology; shell; supercritical flow
Depositing User: Mr Ahmad Suhairi UTP
Date Deposited: 09 Nov 2023 16:19
Last Modified: 09 Nov 2023 16:19
URI: https://khub.utp.edu.my/scholars/id/eprint/8094

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