Effect of different organic amino cations on SAPO-34 for PES/SAPO-34 mixed matrix membranes toward CO2/CH4 separation

Ahmad, N.N.R. and Mukhtar, H. and Mohshim, D.F. and Nasir, R. and Man, Z. (2016) Effect of different organic amino cations on SAPO-34 for PES/SAPO-34 mixed matrix membranes toward CO2/CH4 separation. Journal of Applied Polymer Science, 133 (18). ISSN 00218995

Full text not available from this repository.
Official URL: https://www.scopus.com/inward/record.uri?eid=2-s2....

Abstract

Mixed matrix membranes (MMMs) embedded with functionalized SAPO-34 were successfully synthesized and characterized. Two different types of organic amino cation, namely ethylenediamine (EDA) and hexylamine (HA), were used to functionalize SAPO-34 particles prior to MMM synthesis. In this work, the effects of different functionalizing agents on the membrane morphology, pore size, and CO2/CH4 gas separation properties were investigated. Surface modification of SAPO-34 was confirmed via X-ray photoemission spectroscopy (XPS) where the presence of nitrogen atom was observed for the samples functionalized with amino cations. The dispersion of EDA-functionalized SAPO-34 particles was found to have better polymer/filler interface morphology as shown by field emission scanning electron microscopy (FESEM) analysis. The gas separation performance revealed that PES containing EDA-functionalized SAPO-34 exhibited better CO2/CH4 separation performance as compared to the MMMs containing HA-functionalized SAPO-34. © 2016 Wiley Periodicals, Inc.

Item Type: Article
Additional Information: cited By 23
Uncontrolled Keywords: Carbon dioxide; Field emission microscopes; Membranes; Morphology; Particle size analysis; Photoelectron spectroscopy; Pore size; Positive ions; Scanning electron microscopy; Separation, Ethylene diamine; Field emission scanning electron microscopy; Gas separation performance; Interface morphologies; Membrane morphology; Mixed matrix membranes; Separation performance; X ray photoemission spectroscopy, Gas permeable membranes
Depositing User: Mr Ahmad Suhairi UTP
Date Deposited: 09 Nov 2023 16:18
Last Modified: 09 Nov 2023 16:18
URI: https://khub.utp.edu.my/scholars/id/eprint/7041

Actions (login required)

View Item
View Item