Gholami, Z. and Zabidi, N.A.M. and Gholami, F. and Vakili, M. (2016) Synthesis and characterization of niobium-promoted cobalt/iron catalysts supported on carbon nanotubes for the hydrogenation of carbon monoxide. Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 44 (7). pp. 815-821. ISSN 2097213X
Full text not available from this repository.Abstract
Bimetallic Co/Fe catalysts supported on carbon nanotubes (CNTs) were prepared, and niobium (Nb) was added as promoter to the 70Co�30Fe/CNT catalyst. The physicochemical properties of the catalysts were characterized, and the catalytic performances were analyzed at the same operation conditions (H2�CO (volume ratio)= 2�1, p = 1 MPa, and t = 260�) in a tubular fixed-bed microreactor system. The addition of Nb to the bimetallic catalyst decreases the average size of the oxide nanoparticles and improves the reducibility of the bimetallic catalyst. Evaluation of the catalyst performance in a Fischer-Tropsch reaction shows that the catalyst results in high selectivity to methane, and the selectivity to C5+ increased slightly in the bimetallic catalyst unlike that in the monometallic catalysts. The addition of 1 Nb to the bimetallic catalyst increases CO conversion and selectivity to C5+. Meanwhile, a decrease in methane selectivity is observed. © 2016, Science Press. All right reserved.
Item Type: | Article |
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Additional Information: | cited By 8 |
Uncontrolled Keywords: | Carbon monoxide; Catalyst selectivity; Catalyst supports; Cobalt; Fischer-Tropsch synthesis; Iron compounds; Methane; Nanocatalysts; Niobium; Yarn, Bimetallic catalysts; Bimetallics; Catalytic performance; Fe catalyst; Iron catalyst; Nanotube catalysts; Niobium promoter; Physicochemical property; Synthesis and characterizations, Carbon nanotubes |
Depositing User: | Mr Ahmad Suhairi UTP |
Date Deposited: | 09 Nov 2023 16:18 |
Last Modified: | 09 Nov 2023 16:18 |
URI: | https://khub.utp.edu.my/scholars/id/eprint/6944 |