The role of support morphology on the performance of Cu/ZnO-catalyst for hydrogenation of CO 2 to methanol

Tasfy, S.F.H. and Zabidi, N.A.M. and Shaharun, M.S. and Subbarao, D. (2015) The role of support morphology on the performance of Cu/ZnO-catalyst for hydrogenation of CO 2 to methanol. In: UNSPECIFIED.

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Abstract

The effects of SBA-15 support morphology on the activity of Cu/ZnO catalyst in the hydrogenation of CO 2 to methanol was investigated. In the hydrogenation of CO 2 to methanol at 210°C, 2.25 MPa, H 2 /CO 2 ratio of three remarkable difference was obtained using Cu/ZnO catalyst supported on SBA-15 with different morphology. The catalysts were characterized using N 2 -adsorption, field emission scanning microscopy (FESEM/EDX), transmission electron microscopy (HRTEM), and temperature-programmed reduction (TPR). Characterization of the catalyst showed that support morphology, surface area, metals dispersion, and reducibility influenced the catalytic performance. On the fiber-shaped SBA-15, copper dispersion was 29 whereas on the spherical-shaped SBA-15, the dispersion was 20 . The experimental results showed that the catalyst supported over fiber-shaped SBA-15 exhibit higher CO 2 conversion (13.96 ) and methanol selectivity (91.32 ) compare to catalyst supported over spherical-shaped SBA-15. © 2015 AIP Publishing LLC.

Item Type: Conference or Workshop Item (UNSPECIFIED)
Additional Information: cited By 7; Conference of 23rd Scientific Conference of Microscopy Society Malaysia, SCMSM 2014 ; Conference Date: 10 December 2014 Through 12 December 2014; Conference Code:113582
Depositing User: Mr Ahmad Suhairi UTP
Date Deposited: 09 Nov 2023 16:17
Last Modified: 09 Nov 2023 16:17
URI: https://khub.utp.edu.my/scholars/id/eprint/5860

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