Yousaf, M. and Pervaiz, M. and Zahoor, A.F. and Hussain, A.I. and Khosa, M.K.K. and Ashraf, S. and Sagir, M. and Ashar-Uz-Zaman and Shehzad, K. (2013) Synthesis, characterization and biological studies of bis-μ-2,2'- ethane-1,3-diylbis(nitrilomethylidyne)diphenolatodicopper(II) Using Triple Component Solvent System. Asian Journal of Chemistry, 25 (1). pp. 521-524. ISSN 09707077
Full text not available from this repository.Abstract
The bis-μ-2,2'-ethane-1,3-diyl-bis(nitrilomethylidyne)diphenolato dicopper(II) with the molecular formula Cu2(C16H 14N2O2)2 shows the dimeric complex. Distorted square pyramidal geometry is formed in the community of CuII distinct by the two nitrogen atoms and two oxygen atoms of the N,N'-bis-(salicylidene)- 1,2-ethylene-diamine (ligand) and one oxygen atom commencing both ligand performing as bridge between two ligand molecules, which are wraped in parallel path among each other. In toluene the tilted complex showed crystalline structure but to acquire more apparent X-ray crystallographic data a combination of three solvent (toluene, ethanol, ethyl acetate) was used. The synthesized ligand was analyzed and characterized by mass spectrometry, Fourier transform infrared spectroscopy, nuclear magnetic resonance spectroscopy while the titled compound was characterized by X-ray crystallography and FTIR. The complex and ligand were also engaged for antifungal and antibacterial activities against fungal species A. flavus, A. alternate and A. niger and against bacterial species Staphylococcus aureus, Escheria coli and Bacillus subbtilis. The results of these activities showed that the metal complex has extra antibacterial and antifungal actions than the precursor (ligand) against different culture media.
Item Type: | Article |
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Additional Information: | cited By 10 |
Depositing User: | Mr Ahmad Suhairi UTP |
Date Deposited: | 09 Nov 2023 15:52 |
Last Modified: | 09 Nov 2023 15:52 |
URI: | https://khub.utp.edu.my/scholars/id/eprint/4047 |