Enhancing capacitive performance of magnetite-reduced graphene oxide nanocomposites through magnetic field-assisted ion migration

Jalil, N.A.S.A. and Aboelazm, E. and Khe, C.S. and Ali, G.A.M. and Chong, K.F. and Lai, C.W. and You, K.Y. (2024) Enhancing capacitive performance of magnetite-reduced graphene oxide nanocomposites through magnetic field-assisted ion migration. PLoS ONE, 19 (2 Febr).

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Abstract

The transition towards renewable energy sources necessitates efficient energy storage systems to meet growing demands. Electrochemical capacitors, particularly electric double-layer capacitors (EDLCs), show promising performance due to their superior properties. However, the presence of resistance limits their performance. This study explores using an external magnetic field to mitigate ion transfer resistance and enhance capacitance in magnetite-reduced graphene oxide (M-rGO) nanocomposites. M-rGO nanocomposites with varying weight ratios of magnetite were synthesized and comprehensively characterized. Characterization highlighted the difference in certain parameters such as C/O ratio, the Id/Ig ratio, surface area and particle size that contribute towards alteration of M-rGO�s capacitive behaviour. Electrochemical studies demonstrated that applying a magnetic field increased specific capacitance by approximately 20 and reduced resistance by 33. Notably, a maximum specific capacitance of 16.36 F/g (at a scan rate of 0.1 V/s) and 27.24 F/g (at a current density of 0.25 A/g) was achieved. These improvements were attributed to enhanced ion transportation and migration at the electrode/electrolyte interface, lowering overall resistance. However, it was also observed that the aforementioned parameters can also limit the M-rGO�s performance, resulting in saturated capacitive state despite a reduced resistance. The integration of magnetic fields enhances energy storage in nanocomposite systems, necessitating further investigation into underlying mechanisms and practical applications. © 2024 Abdul Jalil et al. This is an open access article distributed under the terms of the Creative Commons Attribution License,

Item Type: Article
Additional Information: cited By 1
Uncontrolled Keywords: graphene oxide; magnetite; magnetite-reduced graphene oxide; nanocomposite; unclassified drug; graphene oxide; graphite; magnetite, Article; chemical binding; crystal structure; crystallization; current density; cyclic voltammetry; electrochemical analysis; energy dispersive X ray spectroscopy; energy resource; field emission scanning electron microscopy; Fourier transform infrared spectroscopy; impedance spectroscopy; ion transport; magnetic field; magnetic field-assisted ion migration; particle size; Raman spectrometry; renewable energy; surface area; surface property; vibrating sample magnetometry; X ray diffraction; electric capacitance, Electric Capacitance; Ferrosoferric Oxide; Graphite; Magnetic Fields; Nanocomposites
Depositing User: Mr Ahmad Suhairi UTP
Date Deposited: 04 Jun 2024 14:19
Last Modified: 04 Jun 2024 14:19
URI: https://khub.utp.edu.my/scholars/id/eprint/19923

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