Despite the excellent ductility and energy absorption properties of engineered cementitious composites (ECCs), a low modulus of elasticity and excessive drying shrinkage remain some of its major disadvantages. With the current trend in the application of nanotechnology in cementitious composites research, the effect of graphene oxide (GO) on the properties of ECCs is yet to be fully investigated, despite its promising results in ordinary cement paste, mortar, and concrete. ECCs need extensive material tailoring to provide the required mechanical characteristics and controlled fracture size with strain-hardening behavior. Striking a balance between these crucial hardened aspects of ECC without compromising any desired properties is a challenge. Hence, the main aim of the study reported in this paper is to use the response surface methodology (RSM) multi-objective optimization technique to identify an appropriate GO content via the weight of cement and also the volume fraction of polyvinyl alcohol (PVA) fiber as input variables that positively impact ECCs� properties. Using RSM�s central composite design (CCD), 13 mixtures of various combinations of the variables (GO: 0.05, 0.065, 0.08; PVA: 1, 1.5, 2) were developed. Six responses were studied, including compressive strength, direct tensile strength, tensile capacity, flexural strength, modulus of elasticity, Poisson�s ratio, and drying shrinkage. Moreover, the microstructural properties of the composites were assessed using field-emission scanning electron microscopy (FESEM) and mercury intrusion porosimetry (MIP). The outcomes revealed that all the properties of ECCs were significantly enhanced by adding an optimum amount of 0.05 GO and 1�1.5 PVA fiber volume fractions. A maximum increase in 30, 35, 49, and 33.9 in the compressive strength, direct tensile strength, flexural strength, and modulus of elasticity, respectively, of the mixes with 0.05 GO addition was recorded. It is demonstrated that the use of 0.05 GO as a nanoscale particle can provide good outputs for the construction industry. © 2023 by the authors.