In this study, the influence of the orientation of embedded piezoelectric ceramic lead zirconium titanate (PZT) on the mechanical performance of hybrid fiber-reinforced (polypropylene and glass fiber) concrete beams was evaluated. The performance of concrete was evaluated under self-weight, followed by assessing the mechanical property using the electromechanical impedance (EMI) technique after optimization of M30 grade concrete with polypropylene fiber and glass fiber. PZT patches are embedded at different orientations, i.e., 0 deg, 45 deg, and 90 deg, with the axis of the structure for monitoring the hydration of the RC beam. The change in stiffness due to heat hydration in the concrete structure after 5, 7, 14, 21, and 28 days was observed by curing hybrid concrete beams and examining them after 5, 7, 14, 21, and 28 days. On the fifth day, beams were simply supported and allowed to deflect under their weight, and measurements of heat hydration in terms of conductance at frequencies ranging between 1 and 1000 kHz were done. Similarly, days 7, 14, 21, and 28 were done. Day 5 was considered the baseline. It is noted that the PZT sensor placed at an angle of 45 deg is the least effective in recording the incremental changes in hydration that occurred in the concrete beam. The highest quality results were obtained at 90 deg, which is further demonstrated by statistically quantifying the changes using the root-mean-square deviation (RMSD) percentage method and proves to be the most optimized orientation to obtain the stiffness of the hybrid reinforced beam in terms of conductance. © 2023 by ASME.