With advancements in the automated industry, electromagnetic inferences (EMI) have been increasing over time, causing major distress among the end-users and affecting electronic appliances. The issue is not new and major work has been done, but unfortunately, the issue has not been fully eliminated. Therefore, this review intends to evaluate the previous carried-out studies on electromagnetic shielding materials with the combination of Graphene@Iron, Graphene@Polymer, Iron@Polymer and Graphene@Iron@Polymer composites in X-band frequency range and above to deal with EMI. VOSviewer was also used to perform the keyword analysis which shows how the studies are interconnected. Based on the carried-out review it was observed that the most preferable materials to deal with EMI are polymer-based composites which showed remarkable results. It is because the polymers are flexible and provide better bonding with other materials. Polydimethyl-siloxane (PDMS), polyaniline (PANI), polymethyl methacrylate (PMMA) and polyvinylidene fluoride (PVDF) are effective in the X-band frequency range, and PDMS, epoxy, PVDF and PANI provide good shielding effectiveness above the X-band frequency range. However, still, many new combinations need to be examined as mostly the shielding effectiveness was achieved within the X-band frequency range where much work is required in the higher frequency range. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.