Heat integration modeling of hydrogen production from date seeds via steam gasification

Inayat, A. and Shahbaz, M. and Khan, Z. and Inayat, M. and Mofijur, M. and Ahmed, S.F. and Ghenai, C. and Ahmad, A.A. (2021) Heat integration modeling of hydrogen production from date seeds via steam gasification. International Journal of Hydrogen Energy, 46 (59). pp. 30592-30605. ISSN 03603199

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Abstract

The purpose of the current study is to identify the potential of energy-efficient hydrogen (H2) production from date seeds as biomass via steam gasification process along with heat integration in Gulf countries. A reaction kinetics model has been established for steam gasification with in-situ carbon dioxide (CO2) capture of date seeds using MATLAB software. The kinetics of reactions involved in the gasification process was calculated using the optimization parameters fitting approach. The heat integration model has been developed via mixed integer nonlinear programming (MINLP) in MATLAB. In the parametric study, temperature and steam/biomass ratio considered their impact on syngas composition and energy recovery. Results showed that both variables have a strong positive effect on H2 production and depicted maximum production of 68 mol at a temperature of 750 °C with steam/biomass ratio of 1.2. Methane (CH4) and CO2 production were low in the product gas, which showed the activity of water gas shift reaction, methanation reaction, and carbonation reaction. Utilization of waste heat via process heat integration within the system reduced system's external heat load. More than 70 of energy recovered, which could be utilized for gasification and steam production. Energy analysis and process heat integration proved a prospective approach for energy-efficient and sustainable hydrogen production from date seeds. © 2021 Hydrogen Energy Publications LLC

Item Type: Article
Additional Information: cited By 12
Uncontrolled Keywords: Association reactions; Carbon dioxide; Chemical shift; Energy efficiency; Gasification; Hydrogen production; Integer programming; Kinetics; MATLAB; Methanation; Nonlinear programming; Recovery; Steam; Waste heat; Water gas shift, Biomass ratio; Date seeds; Energy efficient; Energy recovery; Gasification process; H-2/ production; Heat integration; Integration models; Process heat integration; Steam gasification, Reaction kinetics
Depositing User: Mr Ahmad Suhairi UTP
Date Deposited: 10 Nov 2023 03:29
Last Modified: 10 Nov 2023 03:29
URI: https://khub.utp.edu.my/scholars/id/eprint/14564

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