Few-layer graphene supported polyaniline (PANI) film as a transparent counter electrode for dye-sensitized solar cells

Shahid, M.U. and Mohamed, N.M. and Muhsan, A.S. and Bashiri, R. and Shamsudin, A.E. and Zaine, S.N.A. (2019) Few-layer graphene supported polyaniline (PANI) film as a transparent counter electrode for dye-sensitized solar cells. Diamond and Related Materials, 94. pp. 242-251. ISSN 09259635

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Abstract

Polyaniline (PANI) is an attractive alternative to platinum counter electrode for dye-sensitized solar cell (DSSC) due to its exceptionally low-cost. However, deposition of PANI film over FTO (Fluorine doped tin oxide) glass surface is very difficult. Here, we demonstrate a novel approach to grow PANI via in-situ polymerization on a porous few-layer graphene (FLG) support which has been prepared by simple solvent exfoliation method and deposited on FTO glass by tape casting. The existence of PANI on few-layer graphene is verified by scanning electron microscopy (SEM) images/energy-dispersive X-ray spectroscopy (EDX) mapping, Raman spectrum, X-ray photoelectron spectroscopy (XPS). While, the presence of PANI in the form of emeraldine salt is confirmed by Fourier transformation infrared spectroscopy (FTIR) and UV-Vis absorbance spectroscopy. DSSC based on Gr/PANI and Pt counter electrode (CE) exhibited photoconversion efficiency (PCE) of 3.58 and 3.97 respectively, under one sun at 1 cm 2 active area. Electrochemical impedance spectroscopy (EIS) reveals that Gr/PANI based symmetrical cells exhibited higher double layer capacitance than Pt based symmetrical cells, believed to be attributed to higher catalytic active sites. However, Gr/PANI and Gr CEs displayed higher charge transfer resistance and Warburg impedance compared to Pt CE, resulting in superior PCE performance for Pt DSSC. Although the PCE of DSSC with Gr/PANI CE could not exceed the DSSC with Pt CE, but its optical properties and photovoltaic performance are comparatively good for consideration as the alternative. © 2019 Elsevier B.V.

Item Type: Article
Additional Information: cited By 26
Uncontrolled Keywords: Charge transfer; Electrochemical electrodes; Electrochemical impedance spectroscopy; Fourier transform infrared spectroscopy; Fourier transforms; Glass; Graphene; Nanocomposites; Optical properties; Photoelectron spectroscopy; Platinum; Polyaniline; Polymer solar cells; Polymerization; Scanning electron microscopy; Solar cells; Tin oxides; Transparent electrodes; X ray photoelectron spectroscopy; X ray spectroscopy, Charge transfer resistance; Counter electrodes; In-situ polymerization; Photoconversion efficiency; Photovoltaic performance; Platinum counter electrodes; Scanning electron microscopy image; Transparent counter electrodes, Dye-sensitized solar cells
Depositing User: Mr Ahmad Suhairi UTP
Date Deposited: 10 Nov 2023 03:26
Last Modified: 10 Nov 2023 03:26
URI: https://khub.utp.edu.my/scholars/id/eprint/11663

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