Production of gasoline range hydrocarbons from catalytic cracking of linoleic acid over various acidic zeolite catalysts

Gurdeep Singh, H.K. and Yusup, S. and Quitain, A.T. and Kida, T. and Sasaki, M. and Cheah, K.W. and Ameen, M. (2019) Production of gasoline range hydrocarbons from catalytic cracking of linoleic acid over various acidic zeolite catalysts. Environmental Science and Pollution Research, 26 (33). pp. 34039-34046. ISSN 09441344

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Abstract

Employment of edible oils as alternative green fuel for vehicles had raised debates on the sustainability of food supply especially in the third-world countries. The non-edible oil obtained from the abundantly available rubber seeds could mitigate this issue and at the same time reduce the environmental impact. Therefore, this paper investigates the catalytic cracking reaction of a model compound named linoleic acid that is enormously present in the rubber seed oil. Batch-scale experiments were conducted using 8.8 mL Inconel batch reactor having a cyclic horizontal swing span of 2 cm with a frequency of 60 cycles per minute at 450 °C under atmospheric condition for 90 min. The performance of HZSM-5, HBeta, HFerrierite, HMordenite and HY catalysts was tested for their efficiency in favouring gasoline range hydrocarbons. The compounds present in the organic liquid product were then analysed using GC-MS and classified based on PIONA which stands for paraffin, isoparaffin, olefin, naphthenes and aromatics respectively. The results obtained show that HZSM-5 catalyst favoured gasoline range hydrocarbons that were rich in aromatics compounds and promoted the production of desired isoparaffin. It also gave a higher cracking activity; however, large gaseous as by-products were produced at the same time. © 2018, Springer-Verlag GmbH Germany, part of Springer Nature.

Item Type: Article
Additional Information: cited By 13
Uncontrolled Keywords: catalysis; catalyst; chemical compound; detection method; experimental study; hydrocarbon; zeolite; zeolite group, gasoline; hydrocarbon; linoleic acid; organic compound; vegetable oil; zeolite, catalysis; chemistry; gas; mass fragmentography; procedures, Catalysis; Gas Chromatography-Mass Spectrometry; Gases; Gasoline; Hydrocarbons; Linoleic Acid; Organic Chemicals; Plant Oils; Zeolites
Depositing User: Mr Ahmad Suhairi UTP
Date Deposited: 10 Nov 2023 03:25
Last Modified: 10 Nov 2023 03:25
URI: https://khub.utp.edu.my/scholars/id/eprint/11203

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