Adsorption characteristics and thermodynamic property fields of polymerized ionic liquid and polyvinyl alcohol based composite/CO2 pairs

Rocky, K.A. and Pal, A. and Moniruzzaman, M. and Saha, B.B. (2019) Adsorption characteristics and thermodynamic property fields of polymerized ionic liquid and polyvinyl alcohol based composite/CO2 pairs. Journal of Molecular Liquids, 294. ISSN 01677322

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Abstract

Consolidated composites are strongly considered as promising adsorbents for adsorption cooling system (ACS) applications. Binder plays a vital role to synthesize consolidated composite. In this study, consolidated composites are synthesized employing highly porous activated carbon (AC) namely Maxsorb III and two types of binders: (i) polymerized ionic liquid (PIL) and (ii) polyvinyl alcohol (PVA) for the development of compact CO2 based ACS. Adsorption characteristics of composite/CO2 pairs are studied at temperature ranging from 20 to 70 °C and pressure up to 7000 kPa. Experimental adsorption uptake data are fitted with Langmuir, Tóth, Dubinin-Astakhov (D-A) and modified D-A equations. It is observed that composite employing 90 wt Maxsorb III and 10 wt PIL shows maximum CO2 adsorption uptake of 1.41146 cm3 g�1, whilst composite incorporating 90 wt Maxsorb III and 10 wt PVA can adsorb up to 1.31311 cm3 g�1. Besides, the adsorption/desorption kinetics and thermodynamic properties such as isosteric heat of adsorption, specific heat capacity, entropy and enthalpy, which are very crucial for ACS design, are rigorously analyzed here. © 2019 Elsevier B.V.

Item Type: Article
Additional Information: cited By 32
Uncontrolled Keywords: Activated carbon; Binders; Carbon dioxide; Cooling systems; Enthalpy; Entropy; Ionic liquids; Polyvinyl alcohols; Specific heat; Thermoelectric equipment, Adsorption characteristic; Adsorption cooling; Adsorption/desorption kinetics; Dubinin-astakhov; Entropy and enthalpies; Isosteric heat of adsorption; Poly (vinyl alcohol) (PVA); Polymerized ionic liquids, Adsorption
Depositing User: Mr Ahmad Suhairi UTP
Date Deposited: 10 Nov 2023 03:25
Last Modified: 10 Nov 2023 03:25
URI: https://khub.utp.edu.my/scholars/id/eprint/11106

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